CESIUM(I) IODIDE

High scintillation yield. Both undoped CsI and thallium-doped CsI [CsI(Tl)] are high-light-output scintillators that efficiently convert X-rays, gamma rays, and charged particles into detectable optical photons.

Superior spatial resolution. Columnar-structured CsI(Tl) films suppress lateral light diffusion, preserving fine image detail for high-resolution digital X-ray flat-panel detectors.

Spectral match with silicon readout. The emission spectrum of CsI(Tl) closely matches the response of silicon photodiode and phototransistor arrays (a-Si, CMOS), ensuring efficient photon collection and high overall detector sensitivity.

Broad application range. CsI-based scintillators are widely deployed in high-energy physics, radiation monitoring and dosimetry, non-destructive testing (NDT), computed tomography (CT), and medical digital radiography.

Product Description

Cesium iodide (CsI) — and thallium-doped CsI [CsI(Tl)] in particular — is an alkali halide scintillator widely deployed in high-energy particle detection and ionizing-radiation instrumentation. Thermally evaporated CsI(Tl) films were among the first scintillator materials adopted for X-ray imaging, coupled to photodiode-based readout systems.

In modern digital X-ray imaging, CsI(Tl) films remain the material of choice owing to their high X-ray-to-light conversion efficiency, a columnar microstructure that preserves spatial resolution, and a close spectral match to silicon photodiode arrays (a-Si, CMOS). Together, these properties deliver high-sensitivity, low-distortion imaging with fine diagnostic detail.

CESIUM(I) IODIDE

Product Parameters

Melting point 626 °C (lit.)
Boiling point 1280 °C
density 4.51 g/mL at 25 °C (lit.)
refractive index 1.7876
Fp 1280°C
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility soluble in ethanol, methanol, acetone
form beads
Specific Gravity4.51
color White
PHpH(50g/l, 25℃) : 5.0~9.0
Water Solubility 74 g/100 mL (20 ºC)
Sensitive Hygroscopic
Merck 142014
Exposure limitsACGIH: TWA 0.01 ppm
Dielectric constant5.6(Ambient)
Stability:Stable. Deliquescent.
CAS DataBase Reference7789-17-5(CAS DataBase Reference)
NIST Chemistry ReferenceCesium iodide(7789-17-5)
EPA Substance Registry SystemCesium iodide (CsI) (7789-17-5)
Hazard Codes Xn,Xi
Risk Statements 36/37/38-42/43-43
Safety Statements 22-36/37-45
RIDADR UN 3077 9 / PGIII
WGK Germany 2
RTECS FL0350000
F 8
TSCA Yes
HS Code 28276000
ToxicityLD50 i.p. in rats: 1.4 g/kg (Cochran)

Application Scenarios

CsI crystals are widely used as scintillator media in electromagnetic calorimeters for high-energy physics experiments. In addition, CsI optical crystals serve as transmission window substrates in Fourier-transform infrared (FT-IR) spectrometers, owing to their broad infrared transmission characteristics.

Compared with the more common potassium bromide (KBr) windows, CsI offers a wider spectral transmission range that extends further into the far-infrared region. However, CsI is relatively soft and lacks well-defined cleavage planes, which makes it more difficult to achieve a flat, high-quality optical polish.

CsI is also hygroscopic and must be stored under dry, desiccated conditions to prevent reaction with atmospheric moisture. Applying a thin germanium (Ge) protective coating to the optical surface effectively mitigates moisture-induced degradation during handling and window replacement.

CESIUM(I) IODIDE

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