Boron Trifluoride Diethyl Etherate

Strong Lewis Acid Catalytic Performance – This boron trifluoride complex delivers robust Lewis acid catalytic activity. It efficiently drives mainstream organic reactions including alkylation, isomerization, hydrocarbon modification and polymerization, greatly boosting synthesis efficiency.

Tunable Reaction Activity via Complexation – It can stably coordinate with oxygen and nitrogen-bearing organic substances. Flexible complex formation enables adjustable catalytic activity, adapting to diversified reaction conditions and process demands.

Safer & More Stable Operation – Compared with gaseous boron trifluoride, the diethyl etherate complex eliminates handling difficulties and volatility risks. It features stable properties and simpler operation for industrial and laboratory use.

Excellent Organic Compatibility – It exhibits superior complexing ability with ethers, amines, phenols, thioethers and their derivatives, possessing wide adaptability for various organic synthesis systems.

Product Description

Boron Trifluoride Diethyl Etherate is a mature, high-activity Lewis acid complex catalyst. Optimized from gaseous boron trifluoride, it overcomes the drawbacks of gaseous raw materials and retains powerful catalytic performance. Its versatile complexing capacity makes it a fundamental catalyst in fine chemical synthesis.

Boron Trifluoride Diethyl Etherate

Product Parameters

Melting point −58 °C(lit.)
Boiling point 126-129 °C(lit.)
Density 1.15 g/mL(lit.)
Vapor density 4.9 (vs air)
Vapor pressure 4.2 mm Hg ( 20 °C)
Refractive index n20/D 1.344(lit.)
Fp 118 °F
Storage temp. Store below +30°C.
Solubility Miscible with ether and alcohol.
Form liquid
Specific Gravity1.126 (20/4℃)
Color brown
Explosive limit5.1-18.2%(V)
Water Solubility Reacts
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Merck 141,350
BRN 3909607
Exposure limitsACGIH: TWA 0.1 ppm; Ceiling 0.7 ppm
StabilityStable. Highly flammable. May form explosive peroxides in contact with air or oxygen. Reacts exothermically with water to form extremely flammable diethyl ether and toxic, corrosive boron trifluoride hydrates. Also incompatible with bases, amines, alkali metals.
InChIKeyMZTVMRUDEFSYGQ-UHFFFAOYSA-N
CAS DataBase Reference109-63-7(CAS DataBase Reference)
NIST Chemistry ReferenceBoron trifluoride etherate(109-63-7)
EPA Substance Registry SystemBoron, trifluoro[1,1'-oxybis[ethane]]-, (T-4)- (109-63-7)

Safety Information

Hazard Codes T,C
Risk Statements 10-14-20/22-35-48/23-34-14/15-23-22
Safety Statements 16-23-26-36/37/39-45-8-28A-43
RIDADR UN 2604 8/PG 1
WGK Germany 3
10
Autoignition Temperature185 °C DIN 51794
TSCA Yes
HazardClass 8
PackingGroup I
HS Code 29319090
Hazardous Substances Data109-63-7(Hazardous Substances Data)

Application Scenarios

It serves as a core cationic polymerization catalyst, widely applied in the production of polyformaldehyde and butadiene rubber. Beyond catalytic synthesis, it acts as a critical raw material for boron isotope separation and preparation of high-energy boron-hydrogen fuels and functional dyes, supporting high-end chemical and new material manufacturing.

Boron Trifluoride Diethyl Etherate

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